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101.
U-Pb analyses of single monazite grains from two granulite facies metapelites in the Ivrea Zone (Southern Alps) reveal the presence, in both samples, of at least three different ages and prove that earlier interpretations of supposedly concordant monazite data as cooling ages are unwarranted. One group of monazite data defines a subconcordant discordia line with an upper intercept age of 293.4 ± 5.8 Ma and a lower intercept age of 210 ± 14 Ma. The upper intercept is interpreted as the real cooling age of the monazites. The lower intercept is interpreted as an episode of fluid-driven Pb-loss, indicated by the presence of internal and external corrosion structures not only of the monazites but also of the zircons in the same samples that are also rejuvenated at 210 ± 12 Ma. Another group of monazite data lies above the concordia. The presence of excess 206Pb indicates that these crystals have grown below the monazite blocking temperature, thus after the granulite facies metamorphism. The age of growth of the new monazite crystals is approached by their 207Pb/235U ages that range between 273 and 244 Ma. The two groups of post-cooling age (post-293.4 ± 5.8 Ma) monazite data correspond to two distinct late- and post-Variscan geotectonic regimes that affected the Southern Alps, (1) Permian transtension with decompression and anatectic melting; (2) Upper Triassic to Lower Jurassic rifting with geographically dispersed hydrothermal activity and alkaline magmatism. Received: 7 July 1998 / Accepted: 4 November 1998  相似文献   
102.
The precise orbit determination antennas of F3/C and GRACE-A satellites are from the same manufacturer, but are installed in different configurations. The current orbit accuracy of F3/C is 3 cm at arcs with good GPS data, compared to 1 cm of GRACE, which has a larger ratio of usable GPS data. This paper compares the qualities of GPS observables from F3/C and GRACE. Using selected satellites and time spans, the following average values for the satellite F3/C and satellite A of GRACE are obtained: multipath effect on the pseudorange P1, 0.78 and 0.38 m; multipath effect on the pseudorange P2, 1.03 and 0.69 m; occurrence frequency of cycle slip, 1/29 and 1/84; standard error of unit weight, 4 and 1 cm; dynamic–kinematic orbit difference, 10 and 2 cm. For gravity determination using F3/C GPS data, a careful selection of GPS data is critical. With six satellites in orbit, F3/C’s large amount of GPS data will make up the deficiency in data quality.  相似文献   
103.
After the catastrophic failure of a red mud reservoir in Hungary, we performed a persistent scatterer radar interferometry (PSI) deformation analysis to investigate the stability and motion history of the entire area focusing on the dam walls of the collapsed structure. Our aim was to contribute to the better understanding of the disaster and, more importantly, to see whether it was possible to prognosticate and consequently prevent the failure of the reservoir and to help avoiding such occurrences worldwide. Our earlier data revealed that the surroundings were generally very stable over the investigated 8 years time interval, whereas significant continuous motions were detected on the embankments. After these first results, we continued our PSI deformation study with the processing and evaluation of the complete ascending pass ENVISAT dataset and later with the combination of the results of the two different observation geometries. From our descending and ascending data, it was possible to combine motions determined in line-of-sight directions and to investigate horizontal and vertical components allowing the estimation of ‘total’ velocity vectors, magnitude and directions, at those locations of the reservoir and on the entire study area where reflections from both projections were available. It was also possible to get information from several other segments of the embankments of the failed reservoir where the descending geometry was unfavorable. With the combination, the complete ENVISAT PSI analysis using both ascending and descending orbit data enabled us to constrain the role of the soil structure and to look at the differential uplift or subsidence due to swelling soil effect. It also enabled us to constrain the role of the deposited mud, slurry, and accumulated water, and the strength and design of the structure in the failure of the red mud reservoir. Models were also constructed to visualize the observed motions of the reservoir embankments and to highlight the location of strain and stress accumulation providing significant constraints on the natural and anthropogenic origin of the disaster.  相似文献   
104.
An initial characterization and performance assessment of the COMPASS/BeiDou-2 regional navigation system is presented. Code and carrier phase measurements on up to three frequencies have been collected in March 2012 with a small regional network of monitoring stations. The signal and measurement quality are analyzed and compared with the Japanese Quasi Zenith Satellite System. A high level of stability is demonstrated for the inter-frequency carrier phase biases, which will facilitate the application of triple-frequency undifferenced ambiguity resolution techniques in future precise point positioning applications. The performance of the onboard Rubidium frequency standards is evaluated in comparison to ground-based hydrogen masers and shown to be well competitive with other GNSS satellite clocks. Precise orbit and clock solutions obtained in post-processing are used to study the presently achievable point positioning accuracy in COMPASS/BeiDou-2-only navigation. Finally, the benefit of triple-frequency measurements and extra-wide-lane ambiguity resolution is illustrated for relative positioning on a short baseline.  相似文献   
105.
106.
Reductive immobilization of uranium by the stimulation of dissimilatory metal-reducing bacteria (DMRB) has been investigated as a remediation strategy for subsurface U(VI) contamination. In those environments, DMRB may utilize a variety of electron acceptors, such as ferric iron which can lead to the formation of reactive biogenic Fe(II) phases. These biogenic phases could potentially mediate abiotic U(VI) reduction. In this work, the DMRB Shewanella putrefaciens strain CN32 was used to synthesize two biogenic Fe(II)-bearing minerals: magnetite (a mixed Fe(II)-Fe(III) oxide) and vivianite (an Fe(II)-phosphate). Analysis of abiotic redox interactions between these biogenic minerals and U(VI) showed that both biogenic minerals reduced U(VI) completely. XAS analysis indicates significant differences in speciation of the reduced uranium after reaction with the two biogenic Fe(II)-bearing minerals. While biogenic magnetite favored the formation of structurally ordered, crystalline UO2, biogenic vivianite led to the formation of a monomeric U(IV) species lacking U-U associations in the corresponding EXAFS spectrum. To investigate the role of phosphate in the formation of monomeric U(IV) such as sorbed U(IV) species complexed by mineral surfaces, versus a U(IV) mineral, uranium was reduced by biogenic magnetite that was pre-sorbed with phosphate. XAS analysis of this sample also revealed the formation of monomeric U(IV) species suggesting that the presence of phosphate hinders formation of UO2. This work shows that U(VI) reduction products formed during in situ biostimulation can be influenced by the mineralogical and geochemical composition of the surrounding environment, as well as by the interfacial solute-solid chemistry of the solid-phase reductant.  相似文献   
107.
In the Variscan Western Tatra granites hybridization phenomena such as mixing and mingling can be observed at the contact of mafic precursors of dioritic composition and more felsic granitic host rocks. The textural evidence of hybridization include: plagioclase?CK-feldspar?Csphene ocelli, hornblende- and biotite-rimmed quartz ocelli, plagioclase with Ca-rich spike zonation, inversely zoned K-feldspar crystals, mafic clots, poikilitic plagioclase and quartz crystals, mixed apatite morphologies, zoned K-feldspar phenocrysts. The apparent pressure range of the magma hybridization event was calculated at 6.1?kbar to 4.6?kbar, while the temperature, calculated by independent methods, is in the range of 810°C?770°C. U-Pb age data of the hybrid rocks were obtained by in-situ LA-MC-ICP-MS analysis of zircon. The oscillatory zoned zircon crystals yield a concordia age of 368?±?8?Ma (MSWD?=?1.1), interpreted as the age of magma hybridization and timing of formation of the magmatic precursors. It is the oldest Variscan magmatic event in that part of the Tatra Mountains.  相似文献   
108.
Reactive mass transport (RMT) simulation is a powerful numerical tool to advance our understanding of complex geochemical processes and their feedbacks in relevant subsurface systems. Thermodynamic equilibrium defines the baseline for solubility, chemical kinetics, and RMT in general. Efficient RMT simulations can be based on the operator-splitting approach, where the solver of chemical equilibria is called by the mass transport part for each control volume whose composition, temperature, or pressure has changed. Modeling of complex natural systems requires consideration of multiphase–multicomponent geochemical models that include nonideal solutions (aqueous electrolytes, fluids, gases, solid solutions, and melts). Direct Gibbs energy minimization (GEM) methods have numerous advantages for the realistic geochemical modeling of such fluid–rock systems. Substantial improvements and extensions to the revised GEM interior point method algorithm based on Karpov’s convex programming approach are described, as implemented in the GEMS3K C/C+?+ code, which is also the numerical kernel of GEM-Selektor v.3 package (http://gems.web.psi.ch). GEMS3K is presented in the context of the essential criteria of chemical plausibility, robustness of results, mass balance accuracy, numerical stability, speed, and portability to high-performance computing systems. The stand-alone GEMS3K code can treat very complex chemical systems with many nonideal solution phases accurately. It is fast, delivering chemically plausible and accurate results with the same or better mass balance precision as that of conventional speciation codes. GEMS3K is already used in several coupled RMT codes (e.g., OpenGeoSys-GEMS) capable of high-performance computing.  相似文献   
109.
110.
We report results of telescope polarimetric imaging of the Moon with a CCD LineScan Camera at large phase angles, near 88°. This allows measurements of the polarization degree with an absolute accuracy better than 0.3% and detection of features with polarization contrast as small as 0.1%. The measurements are carried out in two spectral bands centered near 0.65 and 0.42 μm. We suggest characterizing the lunar regolith with the parameter a(Pmax)A, where Pmax,A, and a are the degree of maximum polarization, albedo, and the parameter describing the linear regression of the correlation Pmax-A. The parameter bears significant information on the particle characteristic size and packing density of the lunar regolith. We also suggest characterizing the lunar regolith with color-ratio images obtained with a polarization filter at large phase angles. We here consider the color-ratios C||(0.65/0.42 μm) and C(0.65/0.42 μm). Using light scattering model calculations we show that the color-ratio images obtained with a polarization filter at large phase angles suggest a new tool to study the lunar surface. In particular, it turns out that the color-ratios C||(0.65/0.42 μm) and C(0.65/0.42 μm) are sensitive to somewhat different thicknesses of the surfaces of regolith particles. We consider the applicability of the Hubble Space Telescope, the Very Large Telescope (ESO), and a spacecraft on a lunar polar orbit for polarimetric observations of the lunar surface.  相似文献   
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